New Laws prohibit people from AVGAS from being sold for automotive applications. If you get busted it isn't just a fine it's a few days in the pokey to boot.
My father is a pilot and I used to work the flightline at Republic airport and Montauk Airport as a kid (no gas at MTP), so the stuff has always been accessible to me. Een now I can still get cans of it. I used to run it in my GTO before I rebuilt the engine because it was one of the few places I could get leaded gas. When I rebuilt the engine I lowered the compression to 9:1 (from stock 10.5:1) and installed hardened valve seats. The car runs like a champ and is as fast as she ever was. In the old days avgas went all the way to 115 octaine, today it is all 100 octaine low lead.
A note about running it in your bike. Unless you have 9.5:1 compression or higher, big cams, etc...Avgas or racing fuel will not help you. It is a common misconception that high octane fuel is a power adder - it is not at all. All it does is allow engines with massive squeeze or high lift /high duration cams to run their optimal by preventing preignition and detonation (pretty much the same thing and can rob power in the same way hitting an upward moving piston with a sledge hammer can rob power). Cam2 lead free 100 octaine is a much better fuel and costs about the same, if I had the choice I would take the cam2.
If you have a bone stock 1970's street bike you should not even think about running premium (92 or 93 octaine), let alone race fuel. Even the vaunted high performance superbikes of the 70's like the cb750 , z1, and gs750 run off of regular. As long as you are tuned up good Reuglar will give you the best performance.
That being said I run premium in my cb750 during the summer months only and here is why: 1) Premium is less likely to contain higher concentrations of ethanol, and 2) I ride in a lot of heavy traffic and a cb750 will begin to detonate when she starts to overheat (sounds like rocks in a coffee can). By running premium the engine can get a little hotter in traffic without detonating. It won't totally prevent it but it buys me a few extra minutes while I figure out my next lane splitting line.